覆油颗粒过滤用玻璃纤维滤材的改性优化
Modification and optimization of glass fiber filter materials for filtering oil-coated particles
摘要:
覆油颗粒是有色金属加工业常见的污染物,主要采用过滤法进行去除。覆油颗粒的高黏特性使其在滤材表面形成大面积的液膜且容易板结,导致滤材阻力增长迅速,使用寿命短。本文对玻璃纤维滤材过滤覆油颗粒的性能进行了优化研究,采用浸渍法制备超亲油滤材,分析了原始滤材和超亲油滤材的运行压降、过滤效率等性能参数的变化规律及原因。结果发现:超亲油改性可以显著降低滤材过滤过程中压降的增长速率,其使用寿命比原始滤材提高了60.76%;同时,超亲油滤材对粒径段在0.3~0.5 μm的小颗粒的过滤效率有约3%的小幅提高。通过观察滤材表面的形貌特征,阻力降低和效率提升的原因在于超亲油滤材对油具有很好的亲和力,油相快速输运到滤材的内部,在纤维上扩散并被吸收,抑制在滤材表面及内部形成液膜。本研究可降低有色金属加工行业中因过滤产生的能耗及减少因滤材频繁更换产生的人工成本。
Abstract:
Oil-coated particles are common pollutants in the non-ferrous metal processing industry, and are mainly removed using filtration methods. The high viscosity of oil-coated particles causes them to form a large liquid film on the surface of the filter material and easily harden, resulting in rapid increase in resistance and short service life of the filter material. This article conducts an optimization study on the filtration performance of oil-coated particles using glass fiber filter materials, and using impregnation method to prepare superoleophilic filter materials, analyses the changes in performance parameters such as operating pressure drop and filtration efficiency of the original filter material and the superoleophilic filter material, as well as the reasons for these changes. The results show that superoleophilic modification can significantly reduce the growth rate of pressure drop during the filtration process of the filter material, and its service life is increased by 60.76% compared to that of the original filter material. At the same time, the superoleophilic filter material has a small increase in filtration efficiency for small particles with a particle size range of 0.3-0.5 μm by about 3%. By observing the morphology characteristics of the filter material surface, the reasons for the reduction in resistance and the improvement in efficiency are that the superoleophilic filter material has a good affinity for the oil, and the oil phase is quickly transported to the interior of the filter material, and diffused and absorbed on the fibers, inhibiting the formation of liquid films on the surface and inside of the filter material. This study is of great significance for reducing the energy consumption due to filtration and labor costs caused by frequent replacement of filter materials in the non-ferrous metal processing industry.
Keywords:oil-coated particle; glass fiber; superoleophilic; surface modification; resistance reduction and efficiency enhancement